Buckwheat Double Chocolate Biscotti

Buckwheat Double Chocolate Biscotti

Crisp, deeply aromatic twice-baked cookies that highlight the earthy, mineral richness of buckwheat flour against bittersweet dark chocolate chunks and cocoa.

1h 50mIntermediate24 biscotti
Remix

Equipment

Digital kitchen scale
Baking sheet
Parchment paper
Medium mixing bowl
Large mixing bowl
Sifter
Whisk
Silicone spatula
Serrated bread knife
Wire cooling rack

Ingredients

24 servings

Dry Ingredients

  • 160 g buckwheat flour, certified gluten-free
  • 30 g unsweetened cocoa powder, Dutch-processed
  • 4 g baking powder
  • 2 g fine sea salt

Wet Ingredients and Sugar

  • 130 g granulated sugar
  • 2 eggs, room temperature
  • 35 g unsalted butter, melted and cooled
  • 5 ml vanilla extract

Inclusions

  • 100 g dark chocolate, chopped into 6mm chunks

Nutrition (per serving)

Nutrition is estimated per serving. Nutrients without complete source data are omitted.

86
Calories
2g
Protein
13g
Carbohydrates
3g
Fat
1g
Fiber
8g
Sugar
59mg
Sodium
Full nutrition
Calories
86 kcal
Protein
2 g
Carbohydrates
13 g
Fat
3 g
Fiber
1 g
Sugar
8 g
Sodium
59 mg
Saturated Fat
2 g
Potassium
88 mg
Calcium
20 mg
Iron
0.9 mg
Magnesium
30 mg
Phosphorus
53 mg
Zinc
0.4 mg
Vitamin A
17 mcg
Vitamin C
0 mg
Water
4 g

Sources: Aggregated Public Data, USDA FoodData Central

Method

01

Preheat the oven to 175°C (350°F) and line a flat baking sheet with parchment paper.

2m
02

Sift the buckwheat flour, cocoa powder, baking powder, and fine sea salt through a sifter into a medium mixing bowl, then briefly whisk to aerate.

3mLook for: Uniform dark dry mixture with no cocoa lumps remaining
03

In a large mixing bowl, beat the eggs and granulated sugar together vigorously with a whisk for 2 to 3 minutes until the mixture turns pale, frothy, and slightly ribbons.

3mLook for: Lightened in color and thick enough to leave faint ribbons when lifted
04

Pour the melted and cooled unsalted butter and vanilla extract into the egg and sugar mixture, whisking gently until thoroughly incorporated.

1mLook for: Smooth, homogenous glossy liquid base
05

Add the sifted dry ingredients into the wet mixture and fold gently using a silicone spatula until a cohesive, slightly tacky dough forms with no dry flour pockets.

2mLook for: Dark chocolate dough pulled completely away from bowl sidesFeel: Soft, thick, and slightly sticky dough
06

Scatter the chopped dark chocolate over the dough and fold with the silicone spatula until the pieces are evenly distributed throughout.

1mLook for: Chocolate chunks uniformly studded across the dough
07

Turn the dough out onto the prepared baking sheet and shape into two logs, each approximately 20 cm (8 inches) long, 6 cm (2.5 inches) wide, and 2 cm (0.8 inches) tall, leaving at least 8 cm (3 inches) of space between them.

5mLook for: Two parallel, smooth, flattened rectangular loaves
08

Bake on the center oven rack at 175°C (350°F) for 25 minutes, ensuring the egg base cooks safely past 71°C (160°F) until the logs are matte, slightly cracked on top, and firm at the outer edges.

25mLook for: Surfaces show slight expansion cracks and a dry, matte appearanceFeel: Top gives slight resistance and edges are set when gently pressed
09

Transfer the baking sheet with the logs directly to a wire cooling rack and allow the logs to cool undisturbed for 25 minutes; they have a crumbly texture hot from the first baking and must cool to gain cutting stability.

25mFeel: Logs feel lukewarm to the touch and firm enough to hold their structure when sliced
10

Transfer one log to a flat cutting surface and cut carefully into 13 mm (1/2 inch) thick slices using a gentle, continuous sawing motion with a serrated bread knife, avoiding downward crushing pressure, then repeat with the second log.

6mLook for: Evenly sliced biscuits approximately 13 mm thick showing exposed chocolate chunks without structural breakage
11

Arrange the sliced biscotti cut-side down in a single layer on the parchment-lined baking sheet, leaving a small gap between each piece for air circulation.

2mLook for: Biscotti laid flat across the baking surface with cut faces fully exposed
12

Return the sheet to the oven at a reduced temperature of 150°C (300°F) and bake for 15 minutes, flipping the slices over halfway through the duration, until completely dried and firm.

15mLook for: Evenly toasted matte cut surfacesFeel: Biscuits feel dry and rigid rather than spongy when tapped
13

Transfer the twice-baked biscotti from the baking sheet onto the wire cooling rack and cool completely for 20 minutes to achieve their signature dry, snappy crunch.

20mFeel: Completely cool to the touch with a brittle, crisp snap

Chef's Notes

  • Buckwheat flour is a botanical seed flour naturally free of gluten; its earthy, mineral profile does not overpower the cookie but instead serves as a grounding backdrop that elevates rich dark chocolate.
  • Because gluten is absent, egg proteins supply the entire structural network for this dough. Maintain exact egg measurements to prevent structural weakness.
  • Always rely on a long, sharp serrated bread knife for slicing the baked logs. Allow the knife teeth to saw gently through the crumb and chocolate chunks rather than pressing straight down.
  • Store fully cooled biscotti in an airtight container at room temperature alongside a food-safe desiccant pack or wrapped tightly in parchment to preserve crispness for up to 2 weeks.

Storage

Freezer: 1 monthFreeze fully cooled biscotti in a rigid airtight container with parchment paper between layers.

Reheating: Warm on a baking sheet at 150°C (300°F) for 5 minutes to restore crispness if softened.

Troubleshooting

Biscotti crumble into uneven pieces during slicing

Cause: The logs were sliced while still hot from the initial bake, or were cut thinner than 13 mm (1/2 inch) without sufficient structural support.

Fix: Cannot be fixed once broken, but broken pieces can still be baked along with whole slices to make crispy cookie clusters.

Prevention: Allow the logs to cool for a full 25 minutes after the first bake, cut strictly at 13 mm (1/2 inch) thickness, and use a light sawing motion with a sharp serrated knife.

Biscotti remain soft or bend slightly after the second baking and cooling

Cause: Insufficient baking time during the second dry-out bake or high atmospheric humidity.

Fix: Return the biscotti to a 150°C (300°F) oven for an extra 5 to 7 minutes, then allow to cool completely on the wire cooling rack.

Prevention: Verify oven temperature with an oven thermometer and ensure biscotti are baked until cut surfaces feel dry and firm.

Cultural Context

Biscotti, traditionally known as cantucci in Tuscany, trace their history back to ancient Roman military rations, perfected during the Renaissance as twice-baked almond biscuits crafted for long storage. While conventional Tuscan versions use wheat flour, alpine Italian regions such as Lombardy have long utilized buckwheat (grano saraceno) in rustic baked goods. This gluten-free recipe honors that alpine tradition, blending hearty buckwheat flour with rich chocolate for a modern interpretation designed to be dunked in espresso or sweet vin santo.

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